Vapor-phase synthesis of low-valent metal-organic frameworks from metal carbonyl synthons

Carl Emil Andersen,James N. McPherson,Mónica Giménez‐Marqués,Jingguo Li, Maiusz Kubus, Satoshi Ito,Christian R. Goeb,Sascha Ott,R. Wugt Larsen, Guillermo Mı́nguez Espallargas,Kasper S. Pedersen

Journal of Materials Chemistry C（2023）

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摘要

We demonstrate the facile vapor-phase synthesis of a novel, porous zero-valent metal–organic framework from the reaction between volatile M(CO) 6 (M = Mo, W) and 4,4'-bipyridine precursors.

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关键词

synthesis,vapor-phase,low-valent,metal-organic

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