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In‐situ Etching Synthesis of Defective CuBTC for CO2/CH4 Separation

Biao Guo,Ruisong Xu,Ke Xu,Jing Liang,Jun Lü,Tonghua Wang,Jinxuan Liu

European Journal of Inorganic Chemistry（2023）

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Abstract
We report a facile in‐situ etching method for the synthesis of defective CuBTC (H‐CuBTC) with hierarchical pore structure. The fabricated mixed matrix membranes (MMMs) containing H‐CuBTC was prepared for the separation of CO 2 /CH 4 , showing superior separation performance due to the defective structure with larger pore size and more open Cu sites, which enhance the interactions between H‐CuBTC and the polymer.
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Key words
defective cubtc,synthesis
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