Donor‐acceptor tin(IV) complexes with α‐diimine and catecholate ligands
European Journal of Inorganic Chemistry(2023)
摘要
Abstract A series of new octahedral bis‐3,6‐di‐tert‐butylcatecholates based on tin(IV) containing metal‐coordinated N‐donor ligands (substituted iminopyridines and diazabutadienes) has been synthesized and structurally characterized. The compounds, both solid and in solution, are intensely colored. They absorb in the visible region of the spectrum. Charge transfer between the catecholate donor and the diimine acceptor is responsible for the absorption. This observation is in good agreement with the DFT calculations and with the electrochemical studies carried out by CV.
更多查看译文
关键词
ligands,complexes
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要