Photo‐Induced α‐Aminoalkylation of Sulfonylarenes with Alkylamines
Chemistry - A European Journal(2023)
摘要
Abstract α‐Aminoalkylation of sulfonylarenes with alkylamines was found to be induced by photoirradiation. Here various types of alkylamines, such as trialkylamines, dialkylamines, N , N ‐dialkylanilines and N ‐alkylanilines as well as sulfonylarenes containing an azole, azine, heterole or benzene ring are available. The reaction proceeds through a homolytic aromatic substitution (HAS) process consisting of addition of an α‐aminoalkyl radical to a sulfonylarene and elimination of the sulfonyl radical to give the α‐arylalkylamine, where photoirradiation is considered to induce homolysis of sulfonylarenes leading to the generation of α‐aminoalkyl radicals that make a radical chain operative.
更多查看译文
关键词
sulfonylarenes
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要