On the usability of salt metathesis reactions for the synthesis of sterically crowded tris-formamidinate Ln(iii ) complexes: success and limits. Spontaneous reduction of Eu(iii ) to Eu(ii )
New Journal of Chemistry(2022)
Abstract
New homoleptic complexes of Eu 3+ and Nd 3+ bearing three bulky N , N ′-bis(diisopropylphenyl)formamidinates were prepared using salt metathesis in a toluene medium. In the presence of THF, the sterically-induced reduction of Eu 3+ to Eu 2+ was observed.
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Key words
salt metathesis reactions,synthesis,complexes,tris-formamidinate
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