Structural dimension modulation in a new oxysulfide system of Ae₂Sb₂O₂S₃ (Ae = Ca and Ba)

Ruiqi Wang,Yantao Zhao,Xian Zhang,Fuqiang Huang

Inorganic chemistry frontiers（2022）

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摘要

Two oxysulfides Ae 2 Sb 2 O 2 S 3 (Ae = Ca, Ba) with different structural dimensions were successfully discovered. Ca 2 Sb 2 O 2 S 3 contains one-dimensional [Sb 2 O 2 S 3 ] 4− chains, while Ba 2 Sb 2 O 2 S 3 features zero-dimensional [Sb 2 O 2 S 3 ] 4− clusters.

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new oxysulfide system,structural dimension modulation

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Structural dimension modulation in a new oxysulfide system of Ae2Sb2O2S3 (Ae = Ca and Ba)

Structural dimension modulation in a new oxysulfide system of Ae₂Sb₂O₂S₃ (Ae = Ca and Ba)