Photoinduced Metal-Free Arylboration of Unactivated Alkenes: Synthesis of Indoline Boronic Ester

The environmentally benign synthesis of indoline boronic esters, especially through a way of arylboration to alkenes, remains a challenge due to the use of transition metals or high-temperature conditions. We described a photoinduced metal-free arylboration of unactivated alkenes for the synthesis of indoline boronic esters and 1,2,3,4tetrahydroquinoline boronic ester in good yields. This approach showed good compatibility and great efficiency for a range of allylphenylamines as well as alkylamine. Remarkably, this transformation also suggested that the base is not necessary for photosensitizer-free diboron reagent mediated mild generation of aryl radical. Furthermore, compared to previously reported methods, this approach is mild and environmentally benign.