Reactivity of a series of triaryl borates, B(OAr^x)₃, in hydroboration catalysis

Tomasz Sokolnicki,Mashael M. Alharbi,Yara van Ingen,Shahnaz Rahim,Milan Pramanik,Alberto Roldan,Jedrzej Walkowiak,Rebecca L. Melen

DALTON TRANSACTIONS（2023）

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摘要

In this paper, we compare the reactivity of a series of triaryl borates B(OArx)(3) as catalysts for the hydroboration of alkenes and alkynes. It was observed that commercially available B(OPh)(3) performed the poorest, whereas catalysts with o-F atoms appeared to perform much better.

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hydroboration catalysis,triaryl borates

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Reactivity of a series of triaryl borates, B(OArx)3, in hydroboration catalysis

Reactivity of a series of triaryl borates, B(OAr^x)₃, in hydroboration catalysis