A p-type semi-conducting copper(I)-1,3-benzenedithiolate 2D coordination polymer with high Seebeck coefficient

Chloe Andrade,Saly Hawila,Ahmad Abdallah,Jean-Luc Rukemampunzi,Adel Mesbah,Nathalie Guillou,Florent Perret,Stefan Wuttke,Thomas Niehaus,Regis Debord,Olivier Boisron,Stephane Pailhes,Aude Demessence

JOURNAL OF MATERIALS CHEMISTRY C（2023）

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摘要

A new p-type semi-conducting and 2D coordination polymer (CP)based on a thiolate ligand and Cu(+I) exhibits a record Seebeck coefficient among CPs, equivalent to that obtained for inorganic compounds. Such a high value originates from the 1D {Cu-S}(n )tubular inorganic network, which is connected through the bridging 1,3-benzenedithiolate ligand.

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关键词

polymer,copperi-13-benzenedithiolate,p-type,semi-conducting

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