Copper-catalyzed 1,2,2-trifunctionalization of maleimides with 1,7-enynes and oxime esters via radical relay/1,5-hydrogen-atom transfer

Li-Lin Jiang,Hui Qiu,Yu Zhou,Ling-Tao Wang,Wen-Hui Yang,Chao Deng,Wen-Ting Wei

Organic Chemistry Frontiers（2023）

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摘要

We describe a novel 1,2,2-trifunctionalization of maleimides with 1,7-enynes and oxime esters through simultaneous construction of four C−C bonds and a C≡N bond in one pot based on the radical relay/1,5-hydrogen-atom transfer (HAT).

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