Facile access to a heterocyclic, sp³-rich chemical scaffold via a tandem condensation/intramolecular nitrone–alkene [3+2] cycloaddition strategy

M. J. Rawling,T. E. Storr,W. A. Bawazir,S. J. Cully,W. Lewis, M. S. I. T. Makki, I. R. Strutt,G. Jones,D. Hamza,R. A. Stockman

Chemical Communications（2015）

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摘要

A heterocyclic, sp3-rich chemical scaffold was synthesised in just 6 steps via a highly regio- and diastereo-selective tandem nitrone formation/intramolecular nitrone–alkene [3+2] cycloaddition reaction.

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Facile access to a heterocyclic, sp3-rich chemical scaffold via a tandem condensation/intramolecular nitrone–alkene [3+2] cycloaddition strategy

Facile access to a heterocyclic, sp³-rich chemical scaffold via a tandem condensation/intramolecular nitrone–alkene [3+2] cycloaddition strategy