Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl ligands: synthesis, structure, and electrochemistry of Mo₂(O)(CO)₂(μ-κ²-S(CH₂)_nS)₂(κ²-diphosphine)

Dalton Transactions（2018）

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摘要

Mixed-valence dimolybdenum complexes Mo2(O)(CO)2{μ-κ2-S(CH2)nS}2(κ2-Ph2P(CH2)mPPh2) (n = 2, 3; m = 1, 2) (1–4) have been synthesized.

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Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl ligands: synthesis, structure, and electrochemistry of Mo2(O)(CO)2(μ-κ2-S(CH2)nS)2(κ2-diphosphine)