Synthesis and coordination chemistry of new asymmetric donor/acceptor pincer ligands, 1,3-C₆H₄(CH₂P^tBu(R_f))₂ (R_f = CF₃, C₂F₅)

Suman Debnath, Gabriel Venegas,Navamoney Arulsamy,Dean M. Roddick

Dalton Transactions（2018）

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摘要

Syntheses of new asymmetric pincer precursors 1,3-C6H4{CH2P(tBu,X)}2 (tBu,XPCPH; X = Cl, SiMe3, OPh) and a new class of hybrid donor/acceptor pincer ligands 1,3-C6H4{CH2P(tBu,Rf)}2 (tBu,RfPCPH; Rf = CF3, C2F5) are reported.

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Synthesis and coordination chemistry of new asymmetric donor/acceptor pincer ligands, 1,3-C6H4(CH2PtBu(Rf))2 (Rf = CF3, C2F5)

Synthesis and coordination chemistry of new asymmetric donor/acceptor pincer ligands, 1,3-C₆H₄(CH₂P^tBu(R_f))₂ (R_f = CF₃, C₂F₅)