Hydrogenase biomimics containing redox-active ligands: Fe₂(CO)₄(μ-edt)(κ²-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe₄–S₄]_H surrogate

Shishir Ghosh,Nathan Hollingsworth,Mark Warren,David A. Hrovat,Michael G. Richmond,Graeme Hogarth

Dalton Transactions（2019）

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摘要

The diiron centre and redox-active diphosphine are reduced in separate steps but there is little evidence of intramolecular electron transfer between the two.

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Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate

Hydrogenase biomimics containing redox-active ligands: Fe₂(CO)₄(μ-edt)(κ²-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe₄–S₄]_H surrogate