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Iron β-diiminate complexes with As2-, As4- and As8-ligands

Fabian Spitzer,Gábor Balázs,Christian Graßl,Manfred Scheer

Chemical Communications（2020）

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Abstract
Depending on the sterics of the flanking group at the β-diiminate ligand at Fe(i) a tetramerisation or dimerisation of As4 units is observed; for the latter case the ligand conformation was influenced by the crystallization temperature.
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