Highly oxidized U(vi) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C₂₇B

Antonio Moreno Vicente, Marc Alias,Paul W. Dunk,Coen de Graaf,Josep M. Poblet,Antonio Rodrı́guez-Fortea

Inorganic chemistry frontiers（2023）

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摘要

The smallest borafullerene U@C 27 B has been synthesized using a laser vaporization cluster source. The U atom, placed in the middle of the cage and interacting with all the 28 atoms, is formally described as highly oxidized U( vi ).

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smallest fullerene,synthesis,gas-phase,boron-doped

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Highly oxidized U(vi) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C27B

Highly oxidized U(vi) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C₂₇B