A copper-catalyzed B–H bond insertion reaction of azide–ynamide with borane adducts via α-imino copper carbenes
Organic chemistry frontiers（2022）
Abstract
A new copper-catalyzed B–H bond insertion into α-imino copper carbenes generated from azide–ynamide cyclization has been developed, leading to a facile and practical synthesis of a series of α-boryl amidines.
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Key words
borane adducts,azide–ynamide,copper-catalyzed
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