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Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors

Cheng‐Pan Zhang,Zhenxing Xi,Kory M. Mueller,Bradley J. Holliday,Hassan S. Bazzi,J. A. Gladysz

Dalton Transactions（2015）

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Abstract
The title compounds, [Q]2[Fe4S4(S(CH2)nRf8)4], feature dianions with four fluorous thiolate ligands and cations that are non-fluorous, “light fluorous”, or “heavy fluorous”; fluorous/organic partition coefficients can reach >93 : <7.
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Key words
sulfur clusters,fluorous analogs,iron/four,redox
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