1H, 31P NMR, Raman and FTIR spectroscopies for investigating phosphoric acid dissociation to understand phosphate ion kinetics in body fluids

Riad Ababneh,Ahmad Telfah,Qais M. Al Bataineh,Elen Tolstik,Johann Dierks,Roland Hergenröder

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy（2024）

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摘要

•Ionic charge carriers and their transport in phosphoric acid-water mixtures from NMR.•Maximum concentration of H3O+ and H2PO4- at mole fractions around 0.8.•Maximum in electrical conductivity and ionic mobility at mole fractions around 0.8.•Water dependence of the viscoelastic and kinematic properties elucidated.•Phosphoric acid dissociation in the DMEM media was studied to understand phosphate ionic kinetics inside the body fluid.

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关键词

Phosphoric acid,Nuclear magnetic resonance (NMR),1H NMR,31P NMR,Ionic formation,Dissociation constant,Self-diffusion coefficient,Raman spectroscopy,FTIR spectroscopy,Body fluids,Phosphate ion

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