Accretionary and collisional processes of the Brasiliano Orogeny recorded by the Tonian La Tuna ophiolite, Dom Feliciano Belt, Uruguay

Accretionary to collisional orogenies such as the Brasiliano Orogeny of eastern South America present the opportunity to distinguish between oceanic-continental (accretionary) and continental (collisional) processes. However, the multitude of geotectonic processes involved and the reduced degree of preservation of the accretionary stage restrain the interpretation of evidence. This study focuses on a metasomatite associated with the La Tuna Ophiolite in the southern Dom Feliciano Belt of the Uruguayan Shield, as these can provide crucial insights into the accretionary stage of the Brasiliano Orogeny. The metasomatite occurs as a meter-sized massive tourmalinite body surrounded by a meter-wide chloritite lens, both enclosed by the La Tuna serpentinite. Our SEM-EDS and EPMA data revealed that the serpentines from the La Tuna ophiolite are antigorite and lizardite, while chlorite was identified as clinochlore. Abundant inclusions of sheridanite chlorite in dravite tourmaline suggests that tourmaline overgrew chlorite. Dravite crystals revealed the presence of three diffuse zones with minor compositional variations, mainly enrichments in Ca and Fe towards the rims. The U-Pb LA-ICP-MS dating of metasomatic zircon yielded ages of 743.2 +/- 3.4 Ma (n = 22) for the chloritite and 743.1 +/- 2.4 Ma (n = 31) for the tourmalinite. High delta B-11 values (+12.1 parts per thousand to + 18.1 parts per thousand) of tourmaline (LA-ICP-MS) suggest that the metasomatic event was caused by seawater-derived fluids in a fluid-dominated environment. The single metasomatic U-Pb age combined with the high delta B-11 values suggest that the metasomatites underwent more intense metasomatic events than those associated with the Bossoroca (-8.5 parts per thousand to +1.8 parts per thousand) and the Ibar & eacute; ophiolites (+3.2 parts per thousand to +5.2 parts per thousand) further north in the S & atilde;o Gabriel Terrane of the Dom Feliciano Belt. Nonetheless, a few spots in tourmaline located within fracture zones and in contact with chlorite displayed negative (c. -5 parts per thousand) and low positive delta B-11 values (c. 2 parts per thousand). These are interpreted as overprinting by crustal fluids, either during the tectonic emplacement of the La Tuna Ophiolite or during exhumation. The calculated T-DM Hf model ages for zircon in tourmalinite and chloritite range from 0.74 to 1.09 Ga and their epsilon Hf(T) values range from +4.9 to +11.2, indicating derivation from depleted mantle sources. The data corroborate earlier results indicating that the associated La Tuna amphibolites have composition similar to N-MORB. Furthermore, the trace element composition of zircon in the metasomatites is consistent with an oceanic environment (U/Yb < 0.1). Geotectonically, the La Tuna metasomatites formed at 743 +/- 2 Ma in an oceanic setting, most likely in a juvenile Adamastor Ocean basin. During the collisional stage of the Brasiliano Orogeny, the La Tuna Ophiolite was tectonically emplaced within the <666 Ma La Micaela Schist of the Paso del Dr & aacute;gon Complex. As such, this study on the La Tuna Ophiolite contributes direct evidence on the oceanic evolution leading up to the accretionary stage of the Brasiliano Orogeny and provides new constraints on the transition towards the collisional stage.