Boosting the visible light photo-thermal catalytic performance of -Bi2O3 by tuning Fe doping amount in carbonylation of isobutyl amine with CO2
Chemical Engineering Science(2024)
摘要
CO2 capture and utilization are viewed as the attractive route to promote carbon neutrality. The alpha-Bi2O3 as a high-performance catalyst of the carbonylation of isobutyl amine with CO2 has been reported in our previous work. Herein, Fe-doped alpha-Bi2O3 with different molar ratios of Fe/Bi (Fe-x%-Bi2O3, x = 1, 3, 5, and 7:100) are further successfully synthesized and used firstly as photo, thermal and photo-thermal catalysts in the carbonylation of isobutyl amine with CO2 to N,N '-diisobutylurea. The result demonstrates the catalytic abilities of alpha-Bi2O3 are significantly boosted by Fe doping and follows an order of Fe-5%-Bi2O3 > Fe-3%-Bi2O3 >> Fe-1%-Bi2O3 > Fe-7%-Bi2O3 > Fe-0%-Bi2O3. Such differences in photo-thermal catalytic performances of Bi2O3 with different Fe doping amounts could be closely linked with the content of both oxygen vacancies and new impurity energy levels in Fe-x%-Bi2O3 based on the further analysis of characterization such as XRD, SEM, Raman, BET, XPS, EPR, UV-vis, PL and TPC.
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关键词
Carbon dioxide,Amines,Carbonylation,Catalysts
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