Construction of a High Spatiotemporal Resolution Dataset of Satellite-Derived p CO2 and Air–Sea CO2 Flux in the South China Sea (2003–2019)
IEEE Transactions on Geoscience and Remote Sensing(2023)
摘要
The South China Sea (SCS) is one of the largest marginal seas in the world. It includes a river-dominated, highly productive ocean margin on the northern shelf and an oligotrophic ocean-dominated basin along with other subregions with various features. It was a challenge to estimate the air–sea CO2 flux in this area. We developed a retrieval algorithm for sea surface partial pressure of CO2 (
${p}$
CO2) by a combination of our previously established mechanistic semianalytical method (MeSAA) and machine learning (ML) method, named MeSAA-ML-SCS, built upon a large dataset of sea surface
${p}$
CO2 collected from in situ measurements during 44 cruises /legs to the SCS in the last two decades. We set several semianalytical parameters, including
${p}$
CO2_therm represented the combined effect of thermodynamics and the atmospheric CO2 forcing on seawater
${p}$
CO 2; upwelling index (UISST) and mixing layer depth (MLD) to characterize the mixing processes; and chlorophyll-a concentration (Chl-a) with remote sensing reflectance at 443 and 555 nm [Rrs(443) and Rrs(555)], which were proxies of biological effects and other characteristics for distinguishing shelf, basin, and subregions. We set the difference between seawater
${p}$
CO2 and atmospheric
${p}$
CO2(
$\boldsymbol {\Delta p}\mathbf {C}\mathbf {O}_{\mathbf {2}}^{\mathbf {Sea{-}Air}}$
) as the output, and the seawater
${p}$
CO2 was finally obtained by summing atmospheric
${p}$
CO2 and
$\boldsymbol {\Delta p}\mathbf {C}\mathbf {O}_{\mathbf {2}}^{\mathbf {Sea{-}Air}}$
. We compared several ML models, and the XGBoost model was confirmed as the best. Independent cruise-based datasets that are not involved in the model training were used to validate the satellite products, with low root-mean-square error (RMSE =
$11.69~\mu $
atm) and mean absolute percentage deviation (APD = 1.59%). The increasing trend of time-series satellite-derived
${p}$
CO2 (2.44 ±
$0.24~\mu$
atm/year) was validated by the in situ data at the Southeastern Asia Time-series Study (SEATS) station, showing good consistency. Results indicate that the SCS as a whole is a source of atmospheric CO2, releasing an average of 12.34 ± 3.11 Tg C/year from a total area of
$2.87\times106$
km2, while the northern shelf acts as a sink (2.02 ± 0.64 Tg C/year). With the forcing of increasing atmospheric CO2, the area-integrated CO2 efflux over the entire SCS is decreasing with a rate of 0.41 Tg C/year during 2003–2019. This shared long time series, high-accuracy dataset (1 km) can be helpful to further improve our understanding of the air–sea CO2 exchange dynamics in the SCS.
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关键词
Air--sea CO₂ flux,machine learning (ML),satellite retrieval,seawater p CO₂,semianalytical algorithm,South China Sea (SCS)
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