Mechanisms of increased small nanoplastic particle retention in water-saturated sand media with montmorillonite and diatomite: Particle sizes, water components, and modelling.

The processes by which small nanoplastics (NPs) accumulate in soil are unclear. To clarify the different deposition processes that affect small NPs (< 30 nm) compared to larger NPs in the soil environment, due to their interaction with clays as major soil components, the transport behavior of two-sized NPs (20 and 80 nm) with two clays (diatomite (Diat) and montmorillonite (Mont)) in NaCl and CaCl2 solutions were investigated in water-saturated quartz sand columns. The experimental results showed that more 20 nm NPs could enter the lattice structure of Diat than Mont in NaCl solution. This contributed to the stronger deposition of 20 nm NPs by Diat on sand, which was associated with a lower k1d/k1 value (obtained from two-site kinetic attachment model). In contrast, 80 nm NPs had a stronger reversible retention than 20 nm NPs with Mont, even though both sizes of NPs-Mont displayed a similar transportability. In CaCl2 solution, the larger NPs-Mont hetero-aggregates formed with a stronger suppressed depth of φmax based on Derjaguin-Landau-Verwey-Overbeek theory. Thus, Mont had a stronger transport inhibition than Diat for both NPs sizes, with a lower k1d/k1. These findings could benefit in predicting the size-based deposition of NPs in a heterogenous soil environment.