Fate of ilmenite as oxygen carrier during 1 MW_th chemical looping gasification of biogenic residues

Chemical looping gasification (CLG) is a novel gasification technology, allowing for the efficient conversion of different solid feedstocks (e.g. biogenic residues) into a high-calorific syngas. As in any chemical looping technology, the oxygen carrier (OC), transporting heat and oxygen from the air to the fuel reactor, is crucial in attaining high process efficiencies. To investigate the fate of the OC during CLG in an industrial environment, ilmenite samples, collected during >400 hours of chemical operation in 1 MWth scale using three different biomass feedstocks, were analyzed using different lab techniques. In doing so, changes in OC particle morphology and composition induced by CLG operation were determined. Moreover, the most important physical and chemical characteristics of the utilized OC were measured. The ensuing dataset allowed for an in-depth evaluation of the CLG technology in semi-industrial scale in terms of OC lifetime and durability. It was found that in the absence of agglomeration, the cycled OC exhibits an oxygen transport capacity of 2.6 wt.-%, a particle density of 3400 kg/m(3 )and particle diameters between 60 and 250 mu m in steady-state conditions. Moreover, it was found that OC loss via particle attrition determines the lifetime of the OC inside the 1 MWth CLG system. On the other hand, feedstock-related agglomeration, observed during CLG operation with wheat straw, was shown to impede OC circulation between AR and FR and thus prevent efficient CLG operation. In summary, the present study thus not only highlights that generally long-term CLG operation in industry-like conditions is feasible, but also provides important insights into measures to improve OC lifetime and durability inside an industrial chemical looping system, such as an optimization of cyclone efficiency or tailored pre-treatment of the utilized feedstock.