An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K)
DALTON TRANSACTIONS(2023)
Abstract
An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142- anion are proposed, in which the NH2BH3- anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13- and B10H15- intermediates were detected.
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