Structure-property relationships in alkoxy substituted benzoates from experimental and computational thermochemistry

Sergey P. Verevkin,Ruslan N. Nagrimanov,Vladimir V. Turovtsev

Chemical Thermodynamics and Thermal Analysis（2023）

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摘要

•Methyl 2-methoxybenzoate studied by combustion calorimetry.•Vapour pressures of methyl methoxy‑benzoates measured by transpiration.•Enthalpies of vaporisation derived and validated.•Theoretical gas phase enthalpy of formation agree with experiment.•Structure-property analysis of thermochemical properties performed.

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关键词

Alkyl methoxy‑benzoates,Combustion calorimetry,Enthalpy of formation,Vapour pressure,Transpiration method,Enthalpy of vaporisation,Group additivity,Hydrogen bonding

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