Visible light-enabled synthesis of phosphorylated indolizine and pyridoindole derivatives via HAT-mediated radical cascade cyclization
ORGANIC & BIOMOLECULAR CHEMISTRY(2023)
摘要
A visible light-enabled cascade cyclization strategy is disclosed with concomitant phosphorylation and heterocycle construction. It provides a novel and environmentally benign approach for accessing tetrahydroindolizine-containing phosphonates under metal-free conditions. Mechanistic studies revealed that phosphinoyl radicals were generated from H-phosphonates via a HAT process.
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关键词
phosphorylated indolizine,pyridoindole derivatives,synthesis,light-enabled,hat-mediated
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