Mg assists in modulating the dimensionalities of the anionic frameworks of borates

Three Mg-containing borates were obtained by high-temperature spontaneous crystallization. In the (A(2)O)- or (A(2)O-MO)-MgO-B2O3 system (A is alkali metal and M is alkaline-earth metal) reported in the ICSD, Li4Mg3SrB12O24 is the first compound that contains one-dimensional infinite anionic chains, and the two examples of the isostructural A(2)Mg(3)B(16)O(28) (A = Rb, Cs) exhibit a two-dimensional infinite bilayer structure for the first time, which contributes to the enrichment of the structural chemistry of Mg-containing borates. Besides, the results of comparison and analysis in this system clearly show that Mg not only affects the anionic frameworks of borates to produce low-dimensional structures but, together with the ratio of N-cation/N-B, is responsible for the dimensionalities of the anionic frameworks in borates. The optical properties of the three compounds also show that they all have short cutoff edges, and Cs2Mg3B16O28, in particular, could reach the deep-ultraviolet region (<200 nm).