Ratiometric analysis of reversible thia-Michael reactions using nitrile-tagged molecules by Raman microscopy
Chemical communications (Cambridge, England)(2023)
摘要
Ratiometric Raman analysis of reversible thia-Michael reactions was achieved using alpha-cyanoacrylic acid (alpha CNA) derivatives. Among alpha CNAs, the smallest derivative, ThioRas (molecular weight: 167 g mol-1), and its glutathione adduct were simultaneously detected in various subcellular locations using Raman microscopy. Ratiometric Raman analysis of reversible thia-Michael reactions was achieved using alpha-cyanoacrylic acid (alpha CNA) derivatives.
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关键词
molecules,reactions,microscopy,thia-michael,nitrile-tagged
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