Time-resolved radioluminescence of the Cu(I) cluster Cu4I62-. Different responses to photo, X-ray, β-ray and α-particle excitation.

John V Garcia, Camilo Guzman,Alexander A Mikhailovsky, Sean Devitt, James R Tinsley, John A DiBenedetto,Peter C Ford

Chemical communications (Cambridge, England)（2023）

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摘要

Time-resolved radioluminescence (TRRL) properties of the Cu(I) cluster Cu4I62- upon pulsed X-ray, β-ray or α-particle excitation are described. The longer (>2 μs) TRRL component displays exponential decay comparable to pulsed UV excitation; however, temporal behaviour at shorter times indicates that high local excited state density provides an alternative decay channel.

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