Double Acylation Product in the SnCl4-promoted Reaction of 4,5-Dichlorocyclopent-4-en-1,3-dione with 1,3,5-Trimethoxybenzene
Russian Journal of Organic Chemistry(2023)
Abstract
Abstract The reaction of 4,5-dichlorocyclopent-4-en-1,3-dione with 1,3,5-trimethoxybenzene under Friedel–Crafts reaction conditions gave, along with the expected 5-(2,4,6-trimethoxyphenyl)-4-chlorocyclopent-4-ene-1,3-dione, a disubstituted product―3,4-bis-(2,4,6-trimethoxyphenyl)-2-chlorocyclopent-2-en-1-one.
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Key words
chlorocyclopentenones,1,3,5-trimethoxybenzene,Friedel-Crafts reaction,5-aryl-4-chlorocyclopentene-1,3-dione,substitution
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