Active Sites in Cr(III)-Based Ethylene Polymerization Catalysts from Machine-Learning-Supported XAS and EPR Spectroscopy

The ethylene polymerization Phillips catalyst has been employed for decades and is central to the polymer industry. While Cr(III) alkyl species are proposed to be the propagating sites, there is so far no direct experimental evidence for such proposal. In this work, by coupling Surface organometallic chemistry, EPR spectroscopy, and machine learning-supported XAS studies, we have studied the electronic structure of well-defined silica-supported Cr(III) alkyls and identified the presence of several surface species in high and low-spin states, associated with different coordination environments. Notably, low-spin Cr(III) sites are shown to participate in ethylene polymerization, indicating that similar Cr(III) alkyl species could be involved in the related Phillips catalyst. Ethylene polymerization catalyst prepared by grafting Cr[CH(SiMe3)2]3 on SiO2 contains well-defined Cr(III) alkyl surface sites, as shown using a combination of ML-supported-XAS and EPR spectroscopies. Furthermore, it is also possible to show by EPR that Cr(III) alkyl sites are competent for olefin insertion.**+image