One-step Formation of Urea from Carbon Dioxide and Nitrogen Using Water Microdroplets

Water (H2O) microdroplets are sprayed onto a graphite mesh covered with a CuBi2O4 coating using a 1:1 mixture of N-2 and CO2 as the nebulizing gas. The resulting microdroplets contain urea [CO(NH2)(2)] as detected by both mass spectrometry and C-13 nuclear magnetic resonance. This gas-liquid-solid heterogeneous catalytic system synthesizes urea in one step on the 0.1 ms time scale. The conversion rate reaches 2.7 mmol g(-1) h(-1) at 25 degrees C and 12.3 mmol g(-1) h(-1) at 65 degrees C, with no external voltage applied. Water microdroplets serve as the hydrogen source and the electron transfer medium for N-2 and CO2 in contact with CuBi2O4. Water-gas and water-solid contact electrification are speculated to drive the reaction process. This strategy couples N-2 fixation and CO2 utilization in an ecofriendly process to produce urea, converting a greenhouse gas into a value-added product.