Tannic Acid and Ca²⁺ Double-Crosslinked Alginate Films for Passion Fruit Preservation

In this study, the interaction of different concentrations of tannic acid (TA) (10%, 20%, and 30% w/w) and Ca2+ with alginate (SA) was utilized to create double-crosslinked SA films. The resulting films were evaluated for their optical, mechanical, water resistance, and barrier properties, and their microstructure and intermolecular interactions were also characterized. The SA films containing 20% TA showed the best mechanical properties, with an observed increase in tensile strength of 22.54%. In terms of water vapor permeability, the SA film containing 30% TA exhibited the highest barrier property, which was 25.36% higher than that of the pure SA film. Moreover, TA demonstrated a strong UV absorption ability, resulting in a nearly 0% UV transmittance of the SA film at 280 nm. It can be seen that SA films containing 20% TA have excellent barrier and mechanical properties, and the development of such films will be applied to the storage and packaging of fresh food. It is worth noting that this work also investigated the effect of SA coatings containing different concentrations of TA on the preservation of passion fruits for 7 days. The results revealed that passion fruits treated with SA coatings containing a 30% TA concentration maintained a better appearance on the 7th day and had the lowest weight loss and crumpling indices of approximately 8.98% and 2.17, respectively, compared to the other treatment groups. Therefore, based on the overall results, the addition of 30% TA to SA coatings proved to be more effective and can be considered a promising approach for delaying fruit senescence and decay.