Synthesis and Characterization of Novel Pd@rGO−CuFe2O4 Magnetic Nanoparticles: A Recyclable Catalyst for C−C Coupling Reaction in Biomass‐Derived Organic Solvent

Yaqoob A. Teli,Reetu Reetu, Priyanka Gurdev Singh, Mayur Jagdishbhai Patel, Sonali Dash, Snehangshu Paine, Poornachandra Shamanna Prabhakar,Virender Singh, Kavya S. Keremane,Nabil Al‐Zaqri,Kalisadhan Mukherjee,Saikat Dutta,Chandi C. Malakar

Asian Journal of Organic Chemistry(2023)

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Abstract
Development of new, cost effective, stable heterogeneous catalyst for the organic transformations is an important thematic area of research. Present work describes the development of new Pd@rGO-CuFe2O4 catalyst and demonstrates its effectiveness for Suzuki-Miyaura type coupling reactions. The additional advantage of this reaction is its feasibility using biomass-derived solvent like gamma-Valerolactone (GVL) in aqueous media. The catalyst is prepared hydrothermally and characterized using XRD, FESEM, EDX, and XPS analysis. The catalyst exhibits excellent activity and recyclability (up to six times) in the C-C coupling reaction to deliver the corresponding biaryl molecules in yields up to 90 %. High efficiency for the conversion of nitriles to amides is also revealed by the prepared catalyst.
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Key words
Amides,Biomass-derived solvent,C−C coupling reaction,Green Chemistry,Heterogeneous catalyst
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