Self-metalation of tetraphenyl porphyrin on Au(111): Structural characterisation via X-ray standing wave analysis

Eleanor S. Frampton,Matthew Edmondson,Chris J. Judd,David A. Duncan,Robert G. Jones,Alex Saywell

INORGANICA CHIMICA ACTA（2023）

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摘要

•Structural characterisation provides mechanistic details of on-surface reactions.•X-ray standing wave (XSW) analysis yields chemical and structural properties.•Self-metalation of a porphyrin on a gold surface is described in three steps.•Close-packed, diffuse, and metalated states are observed and characterised.

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关键词

Tetraphenyl porphyrin,Au(111),Scanning probe microscopy,Normal incidence x-ray standing wave (NIXSW),X-ray photoelectron spectroscopy (XPS),On-surface synthesis

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