A new isochron for stratigraphic correlation in the Permian Delaware Basin and beyond

Altered volcanic ash, preserved as bentonite clay within sedimentary depositional units, can facilitate regional stratigraphic correlation. While many bentonite ash beds have been documented in core extracted over decades of hydrocarbon exploration in the Delaware Basin, a particular -1 cm-thick bentonite has been identified at a distinct stratigraphic position, at a sedimentary facies transition from thin-bedded calciclastic turbidites to thickbedded siliciclastic turbidites, in the compositionally-mixed upper Wolfcamp formation. A comparison of geochemical analyses of the ash from two cores and petrophysical correlations across eight wells was conducted to test the regional correlation of the ash. Despite diagenetic alteration since seafloor deposition -280 Ma, nearly identical geochemical trends between incompatible elemental subsets, including light and heavy rare earth elements, large ion lithophiles, and high field strength elements, suggest that these two ash deposits originated from the same volcanic center. Detailed sedimentologic analyses and lithostratigraphic correlations across three cores spaced tens of km apart confirm that the ash bed is bound by correlative quiescent deepwater strata. Based on the chemical composition, probable timing of deposition, and proximity, we speculate that the Las Delicias Arc produced this ash, and it was transported by wind and deposited as a hemipelagite into the Delaware Basin deep marine environment. This discovery implies the existence of the ash marker in other cores within Late Paleozoic western equatorial Pangea, e.g. in compositionally-mixed deep marine deposits of the Midland Basin and outcropping deposits around the Greater Permian Basin and beyond, which would facilitate regional chronostratigraphic correlation for a critical time in Earth's history.