Energetic bi-diazole 'transformers' toward high-energy thermostable energetic compounds
MATERIALS CHEMISTRY FRONTIERS(2023)
摘要
Seeking a fine balance between high performance and good stability remains a major challenge in designing advanced high-energy-density materials (HEDMs). In this work, a novel energetic molecule, namely 1,1-diamino-3,3 ' ,5,5 ' -tetranitro-4,4 ' -bipyrazole (DATNBP-2), was designed and synthesized through backbone 'transformation'. Though sharing the same elemental composition, compared to 4,4 ' ,5,5 ' -tetranitro-1H,1 ' H-[2,2 ' -biimidazole]-1,1 ' -diamine (DATNBI) and 2,2 ' -diamino-4,4 ' ,5,5 ' -tetranitro-3,3 ' -bipyrazole (DATNBP-1), not only did DATNBP-2 achieve a high room temperature measured density of 1.88 g cm(-3), but also a higher thermal decomposition temperature of 305 degrees C, by far the highest decomposition temperature among the reported analogs. Furthermore, DATNBP-2 possesses a high detonation performance (D-v = 8951 m s(-1), P = 35.9 GPa) and mechanical insensitivity (IS = 40 J, FS > 360 N), outperforming to the traditional benchmark explosives cyclotrimethylnitramine (RDX) and hexanitrostilbene (HNS), rendering it a thermostability energetic material.
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