Enhancing acid orange II degradation in ozonation processes with CaFe₂O₄ nanoparticles as a heterogeneous catalyst

This study used CaFe2O4 nanoparticles as a catalyst for ozonation processes to degrade Acid Orange II (AOII) in aqueous solution. The study compared heterogeneous catalytic ozonation (CaFe2O4/O-3) with ozone treatment alone (O-3) at different pH values (3-11), catalyst dosages (0.25-2.0 g L-1), and initial AOII concentrations (100-500 mg L-1). The O3 alone and CaFe2O4/O-3 systems nearly completely removed AOII's color. In the first 5 min, O3 alone had a color removal efficiency of 75.66%, rising to 92% in 10 min, whereas the CaFe2O4/O-3 system had 81.49%, 94%, and 98% after 5, 10, and 20 min, respectively. The O-3 and CaFe2O4/O-3 systems degrade TOC most efficiently at pH 9 and better with 1.0 g per L CaFe2O4. TOC removal effectiveness reduced from 85% to 62% when the initial AOII concentration increased from 100 to 500 mg L-1. The study of degradation kinetics reveals a pseudo-first-order reaction mechanism significantly as the solution pH increased from 3 to 9. Compared to the O-3 alone system, the CaFe2O4/O-3 system has higher k values. At pH 9, the k value for the CaFe2O4/O-3 system is 1.83 times higher than that of the O-3 alone system. Moreover, increasing AOII concentration from 100 mg L-1 to 500 mg L-1 subsequently caused a decline in the k values. The experimental data match pseudo-first-order kinetics, as shown by R-2 values of 0.95-0.99. AOII degradation involves absorption, ozone activation, and reactive species production based on the existence of CaO and FeO in the CaFe2O4 nanocatalyst. This catalyst can be effectively recycled multiple times.