Phase-modulated built-in electric field to boost photogenerated electron migration for efficient dehalogenation

Meng Ren,Pengjie Zhao,Xinping Fu,Meng Liu,Yuting Ning,Yinjie Zhang,Chunyan Wang,Aijun Lin,Jun Cui

CHEMICAL ENGINEERING JOURNAL（2023）

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Abstract

•A strategy to utilize the phase-modulated built-in electric field is proposed.•An electron migration tunnel and two electron-rich active centers were formed.•The photocatalysis-persulfate cooperative degradation system was constructed.•Excellent detoxification and chain breaking capabilities was achieved.

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Key words

Phase control,Band bending,Built-in electric field,Electron transfer process,Dehalogenation

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