Role of magmatism in efficient gas accumulation in Upper Ordovician-Lower Silurian shales in the Yangtze plate, South China: Evidence from the calcite U-Pb ages and gas C-N isotopes

Shale gas exploration in the Yangtze plate has been hindered by strong heterogeneity of gas compositions resulting from magmatism. Borehole core and gas samples from Upper Ordovician-Lower Silurian in the Upper Yangtze plate and the Lower Yangtze plate were analyzed to explore the effects of magmatism on gas accumulation. The analyses included nitrogen isotope of gas, pore structure and X-ray photoelectron spectroscopy of shales, and U-Pb ages of fracture-filling calcites. Our results suggest that magmatism caused the development of micro-fractures in shale reservoirs and accelerated the thermal evolution rate of organic matter. Magmatism in the Upper Yangtze plate predates the peak of gas generation of Upper Ordovician-Lower Silurian shales. Generation and expulsion of hydrocarbon at high temperatures removes 12C from carbon reservoir. After the magmatism, the continuous subsidence of the strata led to further hydrocarbon generation of organic matter. Moreover, the self-sealing property of shale reservoirs were enhanced by the closure of micro-fractures, development of graphite structures, and enrichment of 13C in residual methane, which favor the efficient accumulation of shale gas. Conversely, magmatism in the Lower Yangtze plate occurred after the peak of gas generation of Upper Ordovician-Lower Silurian shales. Magmatism compromised shale gas reservoirs by disrupting sealing conditions, facilitating methane diffusion and atmospheric nitrogen influx. Additionally, overburden pressure led to the collapse of graphitized OM-hosted pores, further inhibiting gas accumulation. Our findings underscore the pivotal role of magmatism in various stages of shale gas accumulation and are critical for exploration strategies in sedimentary basins with prevalent magmatic activities.