Exceptionally stable double perovskite Sr2-xFeTaO6- as fuel electrode for solid oxide cells
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY(2024)
摘要
Developing fuel electrodes with excellent structural stability and high catalytic activity under various fuel conditions is highly desirable for large-scale applications of solid oxide cells (SOCs). In this study, double perovskite Sr2-xFeTaO6-delta (x = 0, 0.1, 0.2, 0.3) materials were designed as fuel electrodes for SOCs. Sr1.8FeTaO6-delta (S18FT) was synthesized in air, and its structural stability could be maintained in both 5 % H2/Ar and pure CO2 after calcination at 850 degrees C for 10 h. The thermal expansion coefficient of S18FT was 11.8 x 10-6 K-1 at 50-850 degrees C. To further improve the electrochemical performance of the S18FT electrode, it was impregnated with Pd (NO3)2 to form a composite electrode (Pd-SFT-SDC). When hydrogen, propane, ethyl ethanol, and biochar were used as fuels, the maximum power densities of the fuel cells at 850 degrees C were 1114, 370, 474, and 291 mW cm-2, respectively. The fuel cell operated stably for 300 h when using propane. When the solid oxide electrolysis cell mode was used for the co-electrolysis of CO2/H2O, the current density was -0.835 A cm-2 at 1.3 V and 800 degrees C. These results indicated the potential for the use of the Pd-SFT-SDC composite material as a fuel electrode for SOCs.
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关键词
Solid oxide cells,Double perovskite,Stable performance,Electrochemical performance
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