Fabrication of beryllium oxide based fully ceramic microencapsulated nuclear fuels with dispersed TRISO particles by pressureless sintering method

In this research paper, two types of tristructural isotropic (TRISO) particles were dispersed within beryllium oxide (BeO) matrix using the pressureless sintering method to create fully ceramic microencapsulated (FCM) nuclear fuel. The findings indicated that TRISO particles with an outermost layer comprising silicon carbide (SiC) can establish interfacial bonding with BeO matrix, while those with an outermost layer comprising pyrocarbon (OPyC) and BeO matrix exhibit a noticeable gap after the sintering process. Results from transmission electron microscopy (TEM) revealed the presence of an amorphous phase transition zone between SiC and BeO. This zone, according to molecular dynamics (MD) simulation results, is an amorphous phase composed of Be, Si, and O atoms. Overall, TRISO particles with an outermost layer of SiC are more suitable for sintering with BeO matrix than those with an outermost layer of OPyC.