Integrating PtCo Nanoparticles on N, S Doped Pore Carbon Nanosheets As High-Performance Bifunctional Catalysts for Oxygen Reduction and Hydrogen Evolution Reactions

The development of low-Pt bifunctional electrocatalysts with excellent performance for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) is critical for the advancement of the hydrogen economy. Here, we have integrated low-loading Pt and Co metals into N, S doped porous carbon nanosheets to obtain composite catalysts encapsulating PtCo alloy nanoparticles (PtCo2@Co9S8/N-CNS and PtCo2@N-CNS). The acquired PtCo nanoparticles, with dimensions of about 2.5 nm, are uniformly distributed and firmly anchored in N, S doped carbon nanosheets with large specific surface areas and rich pore structure, forming multiple active centers and effectively preventing the aggregation of metal nanoparticles. The PtCo2@Co9S8/N-CNS and PtCo2@N-CNS display high ORR catalytic mass activity of 1.65 A mg(Pt)(-1) and 1.01 A mg(Pt)(-1) in 0.1 M HClO4. The PtCo2@N-CNS catalyst exhibits excellent HER performance in 0.5 M H2SO4, with a mass activity (at 50 mV) 4.3 times higher than that of Pt/C. The PtCo2@Co9S8/N-CNS and PtCo2@N-CNS also exhibit stronger ORR and HER stability than Pt/C after accelerated durability tests. The superior catalytic activity performance of catalysts can be attributed to the synergistic effect of multiple active centers of PtCo, Co9S8 and Co-N in the catalysts. The confinement of PtCo nanoparticles by Co metal and N, S doped porous nanosheets derived from graphitic carbon nitride (g-C3N4) as the template, which can effectively prevent the corrosion and migration of the catalysts under acidic conditions, enhances the catalytic stability of the materials. This study provides a new perspective for the development of economical and efficient bifunctional low-Pt catalysts.