Luminescent rhenium(I) complex with cyanopentafluorophosphate ligand: Synthesis, characterization, and photophysics

Yongyi Feng,Shun-Cheung Cheng,Chi-Chiu Ko

Journal of Organometallic Chemistry（2023）

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摘要

•A strongly luminescent Re(I) complex with anionic cyanopentafluorophosphate [NCPF5]–.•Characterizations of isocyanopentafluorophosphate [CNPF5]– and cyanopentafluorophosphate [NCPF5]– through vibrational spectroscopy.•Detailed investigation revealed the exceptionally strong π-accepting ability of anionic [NCPF5]–.

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关键词

Rhenium, Cyanopentafluorophosphate, MLCT, Phosphorescence, Carbonyl

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