Compositional and structural identification of organic matter contributing to high residual soluble aluminum after coagulation

Understanding the complexation of aluminum (Al) with dissolved organic matter (DOM) is of great significance for the control of residual Al in drinking water after treatment. Here, we used high-resolution and accurate mass measurements to identify the composition and structure of DOM contributing to the formation of soluble organically-bound Al during coagulation at near neutral pH (pH 7.50). The results showed that the organic compounds contributing to soluble organically-bound Al were primarily phenolic compounds and aliphatic compounds. Among them, phenolic compounds with a sulfonic acid group could greatly enhance the hydrolysis of polymeric Al and the formation of high concentrations of monomeric/oligomeric Al-DOM complexes. These organic molecules had a mass-to-charge ratio concentrated below 350. Based on the assumption that oxygencontaining functional groups providing unsaturation in the molecular structure were carboxyl groups, it was inferred that the maximum number of carboxyl groups in phenolic compounds and aliphatic compounds was concentrated between 1-2 and 2-4, respectively. The presence of these molecules was responsible for soluble organically-bound Al accounting for over 80 % of the total soluble Al in the supernatant after coagulation in this study. These findings deepen the understanding of the complexation of Al with DOM. In drinking water treatment plants, the combination of coagulation with processes that can remove such characteristic organics is beneficial for controlling residual Al.