Molecular Engineering of Photosensitizers for Solid-State Dye-Sensitized Solar Cells: Recent Developments and Perspectives

Dye-sensitized solar cells (DSSCs) are a feasible alternative to traditional silicon-based solar cells because of their low cost, eco-friendliness, flexibility, and acceptable device efficiency. In recent years, solid-state DSSCs (ss-DSSCs) have garnered much interest as they can overcome the leakage and evaporation issues of liquid electrolyte systems. However, the poor morphology of solid electrolytes and their interface with photoanodes can minimize the device performance. The photosensitizer/dye is a critical component of ss-DSSCs and plays a vital role in the device's overall performance. In this review, we summarize recent developments and performance of photosensitizers, including mono- and co-sensitization of ruthenium, porphyrin, and metal-free organic dyes under 1 sun and ambient/artificial light conditions. We also discuss the various requirements that efficient photosensitizers should satisfy and provide an overview of their historical development over the years. Recent advances in different types of photosensitizers such as ruthenium, porphyrin, and organic sensitizers are reviewed. The design strategies to develop highly efficient sensitizers and their photovoltaic performance with co-sensitization under 1-sun and artificial light conditions are discussed.image