Catalytic activation of percarbonate with synthesized carrollite for efficient decomposition of bisphenol S: Performance, degradation mechanism and toxicity assessment

This study demonstrates the novel application of carrollite (CuCo2S4) for the activation of sodium percarbonate (SPC) towards bisphenol S (BPS) degradation. The effect of several crucial factors like BPS concentration, CuCo2S4 dosage, SPC concentration, reaction temperature, water matrices, inorganic anions, and pH value were investigated. Experimental results demonstrated that BPS could be efficiently degraded by CuCo2S4-activated SPC system (88.52% at pH = 6.9). The mechanism of BPS degradation by CuCo2S4-activated SPC system was uncovered by quenching and electron spin resonance experiments, discovering that a multiple reactive oxygen species process was involved in BPS degradation by hydroxyl radical (center dot OH), superoxide radical (center dot O-2(-)), singlet oxygen superoxide (O-1(2)) and carbonate radical (center dot CO3-). Furthermore, the S(-II) species facilitated rapid redox cycles between Cu(I)/Cu(II) and Co(II)/Co(III). center dot CO3- was found to not only directly react with BPS molecules, but also act as a bridge to promote center dot O-2(-) and O-1(2) generation, thereby accelerating BPS degradation. Finally, the combination of UHPLC/Q-TOF-MS test with density functional theory (DFT) method was employed to detect major degradation intermediates and thereby elucidate possible reaction pathways of BPS degradation. This study provides a novel strategy by integrating transition metal sulfides with percarbonate for the elimination of organic pollutants in water.