Defying thermodynamics to synthetize hydrazine
Nature Catalysis(2023)
摘要
Selective electrochemical oxidation of ammonia provides an ideal pathway to synthesize hydrazine, but this process is outcompeted by a more favourable overoxidation to N 2 . A molecular ruthenium catalyst has now flipped the script, circumventing the thermodynamic challenges to selectively generate hydrazine.
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关键词
thermodynamics
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