Orthogonal chain collapse in stimuli-responsive di-block polymers leading to self-sorted nanostructures.
Chemical communications (Cambridge, England)(2023)
摘要
We design amphiphilic di-block copolymers (P-b-F and P-b-C) tethered with stimuli-responsive ferrocene and coumarin hydrophobic pendants that exhibit chain collapse behaviour in response to light, redox and chemical cues, with subsequent transformation of the vesicles into micelles. Interestingly, the co-assembled vesicles of the polymer blend under orthogonal stimuli furnish self-sorted micelles and vesicles.
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关键词
polymers,orthogonal chain collapse,stimuli-responsive,di-block,self-sorted
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